Electrochemical Effect of Omega 3 Fatty Acid in Milk at Different Temperatures by Cyclic Voltammetry
DOI:
https://doi.org/10.48112/bcs.v2i3.537Abstract
Abstract Views: 510
In this study, a new method to determine the extent effect of chemical interference between omega 3 fatty acid (fish oil), and milk solution (lactose) was used by electrochemistry procedure through oxidation-reduction of electric current peaks. The different temperature factors and their effect on the oxidation peak of omega-3 in the milk medium were applied to determine the values of activation energy (Ea*) and other thermodynamic values were calculated, such as enthalpy (ΔH*), free energy (ΔG*), and entropy (ΔS*). The results of the analysis showed that there is only one reduction peak of omega 3 fatty acid in milk, which proves that fish oils with lactose milk have an effective antioxidant effect on the body of the organism in addition to the benefits envisaged by these oils. Temperature is the main action to destruction of milk proteins above 50 oC, in addition to the effect of omega-3 on the milk as well.
Keywords:
Cyclic voltammetry, Ea*, Milk, Omega 3 fatty acid, ΔG*, ΔH*, ΔS*References
Abdul-Amir, Y. K., Radhi, M. M., & Al-Mulla, E. A. J. (2017). Use of Nano-Sensors of the Interferences between Pb ((II) with Each of Mg (II), Zn (II), Mn (II), Ca (II), Co (II) and PO 4-3 in Blood Medium: An Electrochemical Study. Nano Biomedicine and Engineering, 9(3), 199-207. https://doi.org/10.5101/nbe.v9i3.p199-207
Atkins, P., & de Paua, J. (2006). Physical chemistry for the life sciences. pg 256-259. New York. Oxford Univeristy Press.
Bao, D., Millare, B., Xia, W., Steyer, B. G., Gerasimenko, A. A., Ferreira, A., ... & Vullev, V. I. (2009). Electrochemical oxidation of ferrocene: a strong dependence on the concentration of the supporting electrolyte for nonpolar solvents. The Journal of Physical Chemistry A, 113(7), 1259-1267. https://doi.org/10.1021/jp809105f
Chapman, S., & Cowling, T. G. (1990). The mathematical theory of non-uniform gases: an account of the kinetic theory of viscosity, thermal conduction and diffusion in gases. Cambridge University Press.
Essa, S. M., & Hoidy, W. H. (2020). Spectrophotometric Determination of Cobalt (Ⅱ) and Lead (Ⅱ) Using (1, 5-Dimethyl-2-Phenyl-4-((2, 3, 4-Trihydroxy Phenyl) Diazenyl)-1H-Pyrazol-3 (2H)-One) as Organic Reagent: Using It as Antimicrobial and Antioxidants. Nano Biomedicine and Engineering, 12(2), 160-166. https://doi.org/10.5101/nbe.v12i2.p160-166
Hosamani, M. T., Ayachit, N. H., & Deshpande, D. K. (2012). Activation energy (Δ G*), enthalpy (Δ H*), and entropy (Δ S*) of some indoles and certain of their binary mixtures. Journal of Thermal Analysis and Calorimetry, 107(3), 1301-1306. https://doi.org/10.1007/s10973-011-1547-0
Kareem, Z. N., Radhi, M. M., & Moosa, A. A. (2021, June). Cyclic Voltammetric Studies of Micro and Nano Paracetamol Using Glassy Carbon Electrode Modified with Multi-Walled Carbon Nanotube and Graphene. In IOP Conference Series: Materials Science and Engineering (Vol. 1105, No. 1, p. 012054). IOP Publishing. https://doi.org/10.1088/1757-899X/1105/1/012054
Machado, J. J., Coutinho, J. A., & Macedo, E. A. (2000). Solid–liquid equilibrium of α-lactose in ethanol/water. Fluid Phase Equilibria, 173(1), 121-134. https://doi.org/10.1016/S0378-3812(00)00388-5
Radhi, M. M., & Al-Mulla, E. A. J. (2015). Use of a grafted polymer electrode to study mercury ions by cyclic voltammetry. Research on Chemical Intermediates, 41(3), 1413-1420. https://doi.org/10.1007/s11164-013-1282-1
Radhi, M. M., Abdullah, H. N., Al-Asadi, S. A., & Al-Mulla, E. A. J. (2015). Electrochemical oxidation effect of ascorbic acid on mercury ions in blood sample using cyclic voltammetry. International Journal of Industrial Chemistry, 6(4), 311-316. https://doi.org/10.1007/s40090-015-0053-9
Radhi, M. M., Abdullah, H. N., Al-Asadi, S. A., & Al-Mulla, E. A. J. (2015). Electrochemical oxidation effect of ascorbic acid on mercury ions in blood sample using cyclic voltammetry. International Journal of Industrial Chemistry, 6(4), 311-316. https://doi.org/10.1007/s40090-015-0053-9
Radhi, M. M., Abdullah, H. N., Jabir, M. S., & Al-Mulla, E. A. J. (2017). Electrochemical effect of ascorbic acid on redox current peaks of CoCl2 in blood medium. Nano Biomedicine and Engineering, 9(2), 103-106. https://doi.org/10.5101/nbe.v9i2.p103-106
Radhi, M. M., Albakry, A. A. A., Jassim, A. M., Alassady, S. A., & Al-Mulla, E. A. J. (2016). Electrochemical study of Pb (II) in present of each ascorbic acid, glucose, urea and uric acid using blood medium as an electrolyte. Nano Biomedicine and Engineering, 8(1), 9-15. https://doi.org/10.5101/nbe.v8i1.p9-15
Radhi, M. M., Alosfur, F. K. M., & Ridha, N. J. (2018). Voltammetric characterization of grafted polymer modified with ZnO nanoparticles on glassy carbon electrode. Russian journal of electrochemistry, 54, 27-32. https://doi.org/10.1134/S1023193518010068
Radhi, M. M., Jaffar Al-Mulla, E. A., & Tan, W. T. (2014). Electrochemical characterization of the redox couple of Fe (III)/Fe (II) mediated by grafted polymer electrode. Research on Chemical Intermediates, 40, 179-192. https://doi.org/10.1007/s11164-012-0954-6
Radhi, M. M., Tan, W. T., Ab Rahman, M. Z., & Kassim, A. B. (2010). Electrochemical characterization of the redox couple of [Fe (CN) 6] 3−/[Fe (CN) 6] 4− mediated by a grafted polymer modified glassy carbon electrode. Journal of chemical engineering of Japan, 43(11), 927-931. https://doi.org/10.1252/jcej.10we150
Sundaram, T. S., Giromini, C., Rebucci, R., Pistl, J., Bhide, M., & Baldi, A. (2022). Role of omega-3 polyunsaturated fatty acids, citrus pectin, and milk-derived exosomes on intestinal barrier integrity and immunity in animals. Journal of Animal Science and Biotechnology, 13(1), 40. https://doi.org/10.1186/s40104-022-00690-7
Tan, W. E., & Goh, J. E. (2008). Electrochemical oxidation of methionine mediated by a fullerene‐C60 modified gold electrode. Electroanalysis: An International Journal Devoted to Fundamental and Practical Aspects of Electroanalysis, 20(22), 2447-2453. https://doi.org/10.1002/elan.200704335
Weintraub, H. S. (2014). Overview of prescription omega-3 fatty acid products for hypertriglyceridemia. Postgraduate medicine, 126(7), 7-18. https://doi.org/10.3810/pgm.2014.11.2828
Zwyea, S., Mohsin, A. A., & Radhi, M. M. (2020). Anti-oxidative effect of sulforaphane compound in blood medium using cyclic voltammetry. EurAsian Journal of Biosciences, 14(2).
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2023 Biomedicine and Chemical Sciences

This work is licensed under a Creative Commons Attribution 4.0 International License.














