Electrochemical Analysis of CuO NPs in Artificial Saliva at Different Concentrations, pH, and Scan Rates Using Cyclic Voltammetry

Authors

  • Maha Hussaien Al-Mhana Dental Techniques Department, Health and Medical Techniques, Middle Technical University, MTU – Iraq
  • Hawraa Khalid Aziz Dental Techniques Department, Health and Medical Techniques, Middle Technical University, MTU – Iraq https://orcid.org/0000-0002-7652-4076
  • Muhammed Mizher Radhi Radiology Techniques Department. Health and Medical Techniques, Middle Technical University, MTU – Iraq

DOI:

https://doi.org/10.48112/bcs.v2i3.475

Abstract

Abstract Views: 90

In this study, the effect of nanoparticles of copper oxide (CuO NPs) dissolved in heat polymerizing acrylic-based soft liner was studied in artificial saliva that was used in the total denture in the mouth was identified, using the electrochemical method, to characterize the extent of the effect of nanoparticles on the oral cavity. Different concentrations (0.3% and 0.5% CuO NPs), pH, scan rates, and reproducibility were studied. The study concluded that the low percentage of 0.3% CuO NPs has less effect than the percentage of 0.5% CuO NPs by redox reaction in the artificial saliva. Furthermore, the acidic pH of the medium has less affected in oxidant that shows reduction peak appeared in the range of pH 2-6, so the nanoparticles of CuO save the acidity of the mouth, while the alkaline pH causes the oxidative effect in the artificial saliva. It can be used the nano copper to improve the chemical properties in the mouth medium.

Keywords:

Artificial Saliva, CuO NPs, Cyclic Voltammetry, pH , Redox

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References

Baliga, S., Muglikar, S., & Kale, R. (2013). Salivary pH: A diagnostic biomarker. Journal of Indian Society of Periodontology, 17(4), 461. https://doi.org/10.4103%2F0972-124X.118317

Brett, C. M., Ioanitescu, I., & Trandafir, F. (2004). Influence of the biological fluid on the corrosion of dental amalgam. Corrosion Science, 46(11), 2803-2816. https://doi.org/10.1016/j.corsci.2004.03.015

Büttner, J., Schneider, T., Westermann, M., & Glei, M. (2022). Artificial digestion of polydisperse copper oxide nanoparticles: investigation of effects on the human in vitro intestinal co-culture model Caco-2/HT29-MTX. Toxics, 10(3), 130. https://doi.org/10.3390/toxics10030130

Fayemi, O. E., Pooe, O. G., Adesanya, F. A., & Ejidike, I. P. (2022). Spectroscopy and Cyclic Voltammetry Properties of SPEEK/CuO Nanocomposite at Screen-Printed Gold Electrodes. Nanomaterials, 12(11), 1825. https://doi.org/10.3390/nano12111825

Ighalo, J. O., Sagboye, P. A., Umenweke, G., Ajala, O. J., Omoarukhe, F. O., Adeyanju, C. A., ... & Adeniyi, A. G. (2021). CuO nanoparticles (CuO NPs) for water treatment: A review of recent advances. Environmental Nanotechnology, Monitoring & Management, 15, 100443. https://doi.org/10.1016/j.enmm.2021.100443

Kilmartin, P. A., Zou, H., & Waterhouse, A. L. (2001). A cyclic voltammetry method suitable for characterizing antioxidant properties of wine and wine phenolics. Journal of agricultural and food chemistry, 49(4), 1957-1965. https://doi.org/10.1021/jf001044u

Piedras, J., Dominguez, R. B., & Gutiérrez, J. M. (2021). Determination of uric acid in artificial saliva with compact AMP3291 reader and Au nanoparticles modified electrode. Chemosensors, 9(4), 73. https://doi.org/10.3390/chemosensors9040073

Pokrowiecki, R., Wojnarowicz, J., Zareba, T., Koltsov, I., Lojkowski, W., Tyski, S., ... & Zawadzki, P. (2019). Nanoparticles and human saliva: a step towards drug delivery systems for dental and craniofacial biomaterials. International Journal of Nanomedicine, 9235-9257.

Radhi, M. M., & Al-Mulla, E. A. J. (2015). Use of a grafted polymer electrode to study mercury ions by cyclic voltammetry. Research on Chemical Intermediates, 41(3), 1413-1420. https://doi.org/10.1007/s11164-013-1282-1

Radhi, M. M., Abdullah, H. N., Al-Asadi, S. A., & Al-Mulla, E. A. J. (2015). Electrochemical oxidation effect of ascorbic acid on mercury ions in blood sample using cyclic voltammetry. International Journal of Industrial Chemistry, 6(4), 311-316. https://doi.org/10.1007/s40090-015-0053-9

Radhi, M. M., Abdullah, H. N., Jabir, M. S., & Al-Mulla, E. A. J. (2017). Electrochemical effect of ascorbic acid on redox current peaks of CoCl 2 in blood medium. Nano Biomedicine and Engineering, 9(2), 103-106. https://doi.org/10.5101/nbe.v9i2.p103-106

Radhi, M. M., Alosfur, F. K. M., & Ridha, N. J. (2018). Voltammetric characterization of grafted polymer modified with ZnO nanoparticles on glassy carbon electrode. Russian Journal of Electrochemistry, 54, 27-32. https://doi.org/10.1134/S1023193518010068

Radhi, M. M., Ibrahim, A. I., Al-Haidarie, Y. K., Al-Asadi, S. A., & Al-Mulla, E. A. J. (2019). Rifampicin: Electrochemical effect on blood component by cyclic voltammetry using nano-sensor. Nano Biomedicine and Engineering, 11(2), 150-156. https://doi.org/10.5101/nbe.v11i2.p150-156

Reddy, S., Swamy, B. K., & Jayadevappa, H. (2012). CuO nanoparticle sensor for the electrochemical determination of dopamine. Electrochimica Acta, 61, 78-86. https://doi.org/10.1016/j.electacta.2011.11.091

Saleh, T. N. K. (2015). Influence of temperature and pH on corrosion resistance of Ni–Cr and Co–Cr dental alloys on oral environment (Doctoral dissertation, Cape Peninsula University of Technology). https://etd.cput.ac.za/handle/20.500.11838/2400

Shafaee, H., Khosropanah, H., Rahimi, H., Darroudi, M., & Rangrazi, A. (2022). Effects of Adding Cinnamon, ZnO, and CuO Nanoparticles on the Antibacterial Properties of a Glass Ionomer Cement as the Luting Agent for Orthodontic Bands and Their Cytotoxicity. Journal of Composites Science, 6(11), 336. https://doi.org/10.3390/jcs6110336

Vázquez, M. E., López, J. R., Medina-Rodelo, D., Jiménez-Edeza, M., Castaneda-Ruelas, G. M., López, A. M., ... & Méndez, P. F. (2019). Electrochemical study, structural characterization and antimicrobial activity of Silver and Copper Oxide (CuO) nanoparticles synthesized by a Green Method Using L-ascorbic Acid and Chitosan. International journal of electrochemical science, 14(7), 6366-6375. https://doi.org/10.20964/2019.07.04

Zampardi, G., Thöming, J., Naatz, H., Amin, H. M., Pokhrel, S., Mädler, L., & Compton, R. G. (2018). Electrochemical behavior of single CuO nanoparticles: implications for the assessment of their environmental fate. Small, 14(32), 1801765. https://doi.org/10.1002/smll.201801765

Electrochemical Analysis of CuO NPs in Artificial Saliva at Different Concentrations, pH, and Scan Rates Using Cyclic Voltammetry

Published

2023-07-01

How to Cite

Al-Mhana, M. H., Aziz, H. K., & Radhi, M. M. (2023). Electrochemical Analysis of CuO NPs in Artificial Saliva at Different Concentrations, pH, and Scan Rates Using Cyclic Voltammetry. Biomedicine and Chemical Sciences, 2(3), 198–202. https://doi.org/10.48112/bcs.v2i3.475

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Articles