New Homo and Heterobinuclear Macrocyclic Complexes Bearing Isatine

Structural Characterization, Thermal Study and DFT Calculations

Authors

  • Anaam Rasheed Department of Chemistry, College of Science, Mustanseriyah University, Baghdad - Iraq
  • Senan Albayati Department of Chemistry, College of Science, Mustanseriyah University, Baghdad - Iraq https://orcid.org/0000-0001-5343-0862
  • Sarab Alazawi Department of Chemistry, College of Science, Mustanseriyah University, Baghdad - Iraq
  • Enas Zuhair Department of Chemistry, College of Science, Mustanseriyah University, Baghdad - Iraq
  • Mudeer Merza Department of Chemistry, College of Science, Mustanseriyah University, Baghdad - Iraq https://orcid.org/0000-0001-7060-8482
  • Khalil Abid Department of Chemistry, College of Science, Mustanseriyah University, Baghdad - Iraq

DOI:

https://doi.org/10.48112/bcs.v1i3.187

Abstract

Abstract Views: 216

A new metal-free macrocyclic Schiff base ligand bearing two metal cavities incorporated with two sets of N3O2 donor atoms derived from 2, 6-diaminopyridine and isatine was synthesized. The new ligand was used to prepare homo and hetero binuclear macrocyclic Schiff base complexes with Ni (II), Cu (II), ZrO (II) and Ba (II) metal ions. The ligand and metal complexes were characterized using Fourier transform infrared (FT-IR), UV–vis, mass spectroscopy, elemental analysis (CHN), thermo gravimetric analysis (TGA), magnetic susceptibility, and molar conductivity measurements. The DFT calculations using the B3LYP functional method have been applied to obtain the geometry and electronic properties of the ligand and its metal complexes to support the experimental data. To describe the reactivity of the title molecules, the HOMO and LUMO levels and Mulliken atomic charges were determined.

Keywords:

Bimetal Complexes, Diaminopyridine, Schiff Base, Supermolecule Ligands

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References

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New Homo and Heterobinuclear Macrocyclic Complexes Bearing Isatine

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Published

2022-07-01

How to Cite

Rasheed, A., Albayati, S., Alazawi, S., Zuhair, E., Merza, M., & Abid, K. (2022). New Homo and Heterobinuclear Macrocyclic Complexes Bearing Isatine: Structural Characterization, Thermal Study and DFT Calculations. Biomedicine and Chemical Sciences, 1(3), 138–146. https://doi.org/10.48112/bcs.v1i3.187

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Vol. 1 No. 3 (2022)

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Articles

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